Phthalocyanine Doped Metal Oxide Nanoparticles on Multiwalled Carbon Nanotubes Platform for the detection of Dopamine
International journal of scientific report, 23 p.
-д хадгалсан:
| Үндсэн зохиолчид: | , , , , |
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| Формат: | Сэтгүүл |
| Хэл сонгох: | англи |
| Хэвлэсэн: |
Springer publishing
2020
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| Нөхцлүүд: | |
| Онлайн хандалт: | https://ir.oauife.edu.ng/handle/123456789/5113 |
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| _version_ | 1810764574707679232 |
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| author | Mphuthi, Ntsoaki Adekunle, Abolanle S. Fayemi, Omolola E. Olasunkanmi, Lukman O. Ebenso, Eno E. |
| author_facet | Mphuthi, Ntsoaki Adekunle, Abolanle S. Fayemi, Omolola E. Olasunkanmi, Lukman O. Ebenso, Eno E. |
| author_sort | Mphuthi, Ntsoaki |
| collection | DSpace |
| description | International journal of scientific report, 23 p. |
| format | Journal |
| id | oai:ir.oauife.edu.ng:123456789-5113 |
| institution | My University |
| language | English |
| publishDate | 2020 |
| publisher | Springer publishing |
| record_format | dspace |
| spelling | oai:ir.oauife.edu.ng:123456789-51132023-05-13T11:10:23Z Phthalocyanine Doped Metal Oxide Nanoparticles on Multiwalled Carbon Nanotubes Platform for the detection of Dopamine Mphuthi, Ntsoaki Adekunle, Abolanle S. Fayemi, Omolola E. Olasunkanmi, Lukman O. Ebenso, Eno E. Phthalocyanine Metal Oxide electrocatalytic nanoparticles Electrocatalytic oxidation International journal of scientific report, 23 p. The electrocatalytic properties of metal oxides (MO=Fe3O4, ZnO) nanoparticles doped phthalocyanine (Pc) and functionalized MWCNTs, decorated on glassy carbon electrode (GCE) was investigated. Successful synthesis of the metal oxide nanoparticles and the MO/Pc/MWCNT composite were confirmed using UV-Vis, EDX, XRD and TEM techniques. Successful modification of GCE with the MO and their composite was also confirmed using cyclic voltammetry (CV) technique. GCE-MWCNT/ ZnO/29H,31H-Pc was the best electrode towards DA detection with very low detection limit (0.75μM) which compared favourably with literature, good sensitivity (1.45μA/μM), resistance to electrode fouling, and excellent ability to detect DA without interference from AA signal. Electrocatalytic oxidation of DA on GCE-MWCNT/ZnO/29H,31H-Pc electrode was diffusion controlled but characterized with some adsorption of electro-oxidation reaction intermediates products. The fabricated sensors are easy to prepare, cost effective and can be applied for real sample analysis of dopamine in drug composition. The good electrocatalytic properties of 29H,31H-Pc and 2,3-Nc were related to their (quantum chemically derived) frontier molecular orbital energies and global electronegativities. The better performance of 29H,31H-Pc than 2,3-Nc in aiding electrochemical oxidation of DA might be due to its better electron accepting ability, which is inferred from its lower ELUMO and higher χ. 2020-01-21T11:48:58Z 2020-01-21T11:48:58Z 2017-03-03 Journal Mphuthi, Ntsoaki & Adekunle, Abolanle & Fayemi, Omolola & Olasunkanmi, Lukman & Ebenso, Eno. (2017). Phthalocyanine Doped Metal Oxide Nanoparticles on Multiwalled Carbon Nanotubes Platform for the detection of Dopamine. Scientific Reports. 7. 43181. 10.1038/srep43181. DOI: 10.1038/srep43181 https://ir.oauife.edu.ng/handle/123456789/5113 en application/pdf Springer publishing |
| spellingShingle | Phthalocyanine Metal Oxide electrocatalytic nanoparticles Electrocatalytic oxidation Mphuthi, Ntsoaki Adekunle, Abolanle S. Fayemi, Omolola E. Olasunkanmi, Lukman O. Ebenso, Eno E. Phthalocyanine Doped Metal Oxide Nanoparticles on Multiwalled Carbon Nanotubes Platform for the detection of Dopamine |
| title | Phthalocyanine Doped Metal Oxide Nanoparticles on Multiwalled Carbon Nanotubes Platform for the detection of Dopamine |
| title_full | Phthalocyanine Doped Metal Oxide Nanoparticles on Multiwalled Carbon Nanotubes Platform for the detection of Dopamine |
| title_fullStr | Phthalocyanine Doped Metal Oxide Nanoparticles on Multiwalled Carbon Nanotubes Platform for the detection of Dopamine |
| title_full_unstemmed | Phthalocyanine Doped Metal Oxide Nanoparticles on Multiwalled Carbon Nanotubes Platform for the detection of Dopamine |
| title_short | Phthalocyanine Doped Metal Oxide Nanoparticles on Multiwalled Carbon Nanotubes Platform for the detection of Dopamine |
| title_sort | phthalocyanine doped metal oxide nanoparticles on multiwalled carbon nanotubes platform for the detection of dopamine |
| topic | Phthalocyanine Metal Oxide electrocatalytic nanoparticles Electrocatalytic oxidation |
| url | https://ir.oauife.edu.ng/handle/123456789/5113 |
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