COMPARATIVE STUDY OF THE MID-IR SPECTROSCOPY AND CHEMICAL METHOD FOR SOIL PHYSICAL AND CHEMICAL PROPERTIES

Mid-IR spectroscopy is a fast soil analytical tool and can serve as alternative to the time consuming and hazardous chemical methods for the determination of soil physical and chemical analyses. To determine the degree of correlation between these two methods, 110 soil samples from the derived savan...

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Hlavní autoři: Ojo, A O, Olalekan, O O, Ande, O T, Adeoyolanu, O D, Are, K S, Adelana, A O, Oke, A O, Denton, O A, Oyedele, A O
Médium: Online
Jazyk:angličtina
Vydáno: The Faculty of Agriculture Obafemi Awolowo University, Ile-Ife, Nigeria. 2017
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On-line přístup:https://ija.oauife.edu.ng/index.php/ija/article/view/58
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author Ojo, A O
Olalekan, O O
Ande, O T
Adeoyolanu, O D
Are, K S
Adelana, A O
Oke, A O
Denton, O A
Oyedele, A O
author_facet Ojo, A O
Olalekan, O O
Ande, O T
Adeoyolanu, O D
Are, K S
Adelana, A O
Oke, A O
Denton, O A
Oyedele, A O
author_sort Ojo, A O
collection OJS
description Mid-IR spectroscopy is a fast soil analytical tool and can serve as alternative to the time consuming and hazardous chemical methods for the determination of soil physical and chemical analyses. To determine the degree of correlation between these two methods, 110 soil samples from the derived savanna region of Nigeria were analyzed using both chemical and spectroscopic methods. The MIR absorbance spectra were recorded in the range of 4000 to 400 cm-1 (2500-25000 nm) with 110 scans. Before the absorbance spectra were calibrated to predict soil properties, principal component analysis was conducted to detect sample outliers (6 out of 110 scans were identified as outliers) in the raw data set of the spectra and excluded. Satisfactory predictions (r2 = 0.65 - 0.75) were obtained for sand, silt and clay as regards the physical properties as well as total C, total N, P, Ca, Mg, K, Mn, Fe, Cu ( all determined using mehlich-3 extractant) for soil chemical properties. However, poorer predictions (r2 = 0.61-0.64) were obtained for mehlich 3-Na and Zn only.  With this high degree of prediction, it can be concluded that mid-IR spectroscopy has the potential to provide rapid and cost effective estimates of some soil physical and chemical properties.
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spelling oai:ojs2.ija.oauife.edu.ng:article-582019-01-14T14:50:36Z COMPARATIVE STUDY OF THE MID-IR SPECTROSCOPY AND CHEMICAL METHOD FOR SOIL PHYSICAL AND CHEMICAL PROPERTIES Ojo, A O Olalekan, O O Ande, O T Adeoyolanu, O D Are, K S Adelana, A O Oke, A O Denton, O A Oyedele, A O mid-IR spectroscopy, chemical methods, soil physical properties, soil chemical properties Mid-IR spectroscopy is a fast soil analytical tool and can serve as alternative to the time consuming and hazardous chemical methods for the determination of soil physical and chemical analyses. To determine the degree of correlation between these two methods, 110 soil samples from the derived savanna region of Nigeria were analyzed using both chemical and spectroscopic methods. The MIR absorbance spectra were recorded in the range of 4000 to 400 cm-1 (2500-25000 nm) with 110 scans. Before the absorbance spectra were calibrated to predict soil properties, principal component analysis was conducted to detect sample outliers (6 out of 110 scans were identified as outliers) in the raw data set of the spectra and excluded. Satisfactory predictions (r2 = 0.65 - 0.75) were obtained for sand, silt and clay as regards the physical properties as well as total C, total N, P, Ca, Mg, K, Mn, Fe, Cu ( all determined using mehlich-3 extractant) for soil chemical properties. However, poorer predictions (r2 = 0.61-0.64) were obtained for mehlich 3-Na and Zn only.  With this high degree of prediction, it can be concluded that mid-IR spectroscopy has the potential to provide rapid and cost effective estimates of some soil physical and chemical properties. The Faculty of Agriculture Obafemi Awolowo University, Ile-Ife, Nigeria. 2017-11-03 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Peer-reviewed Article application/pdf https://ija.oauife.edu.ng/index.php/ija/article/view/58 Ife Journal of Agriculture; Vol. 29 No. 1 (2017): Ife Journal of Agriculture; 52-62 0331-6351 eng https://ija.oauife.edu.ng/index.php/ija/article/view/58/59 Copyright (c) 2017 Ife Journal of Agriculture
spellingShingle mid-IR spectroscopy, chemical methods, soil physical properties, soil chemical properties
Ojo, A O
Olalekan, O O
Ande, O T
Adeoyolanu, O D
Are, K S
Adelana, A O
Oke, A O
Denton, O A
Oyedele, A O
COMPARATIVE STUDY OF THE MID-IR SPECTROSCOPY AND CHEMICAL METHOD FOR SOIL PHYSICAL AND CHEMICAL PROPERTIES
title COMPARATIVE STUDY OF THE MID-IR SPECTROSCOPY AND CHEMICAL METHOD FOR SOIL PHYSICAL AND CHEMICAL PROPERTIES
title_full COMPARATIVE STUDY OF THE MID-IR SPECTROSCOPY AND CHEMICAL METHOD FOR SOIL PHYSICAL AND CHEMICAL PROPERTIES
title_fullStr COMPARATIVE STUDY OF THE MID-IR SPECTROSCOPY AND CHEMICAL METHOD FOR SOIL PHYSICAL AND CHEMICAL PROPERTIES
title_full_unstemmed COMPARATIVE STUDY OF THE MID-IR SPECTROSCOPY AND CHEMICAL METHOD FOR SOIL PHYSICAL AND CHEMICAL PROPERTIES
title_short COMPARATIVE STUDY OF THE MID-IR SPECTROSCOPY AND CHEMICAL METHOD FOR SOIL PHYSICAL AND CHEMICAL PROPERTIES
title_sort comparative study of the mid ir spectroscopy and chemical method for soil physical and chemical properties
topic mid-IR spectroscopy, chemical methods, soil physical properties, soil chemical properties
topic_facet mid-IR spectroscopy, chemical methods, soil physical properties, soil chemical properties
url https://ija.oauife.edu.ng/index.php/ija/article/view/58
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